Biography
Kyung-Soo Park received his PhD from the Department of Advanced Materials Science and Engineering of Korea University in 2011. Now he is a senior research scientist in Institute for Advanced Engineering (IAE). His research interest includes recycling of e-waste and waste glass. Chan Gi Lee received Doctoral degree at Kyushu University in 2009. He was Post-Doctoral Fellow in Micro-space Chemistry Solution team, Measurement Solution Research Center (MSRC), National Institute of Advanced Industrial Science and Technology (AIST), Japan. Now he is a principal research engineer in Institute for Advanced Engineering (IAE). His research interests include synthesis of nanomaterials and material recycling
Abstract
A three-step, batch type recovery method was developed to produce indium powders from dilute indium chloride solutions prepared by dissolving indium tin oxide (ITO) electrodes from waste liquid crystal display (LCD) panels in concentrated hydrochloric acid (HCl) solutions. A 5-L batch process was used with individual experimental parameters for cementation, such as temperature and time, which were varied to optimize their eff ects on the physicochemical properties and purity of the recovered indium powders and the recovery rate. A validation experiment was performed by preparing indium bearing solutions in a 5-180 min kinetic study of indium cementation with aluminum in aqueous HCl solutions at 65ºC. Th e indium powders obtained from the cementation processes were further characterized using various analytical tools, such as ICP/AES, X-ray diff raction (XRD), and scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS). Cementation at 60ºC for 10 min resulted in the optimal process effi ciency, with a recovery rate and indium purity of 70 and 99.8% respectively
Biography
Karolina Matuszek, has completed her study in 2012 from Silesian University of Technology, Faculty of Chemistry, specialization Chemical Technology. She is a third grade PhD student in the Department of Chemical Organic Technology and Petrochemistry at Silesian University of Technology, Faculty of Chemistry (Gliwice, Poland). Her main fields of interests are: chemical technology, green chemistry, oxidation processes, alkylation processes and ionic liquids
Abstract
Over the past 20 years, ionic liquids, supercritical fluids and water have become powerful alternatives to conventional organic solvents. Because of their properties, which include an undetectable vapour pressure, the ability to dissolve numerous organic and inorganic substances, high thermal stability, and a wide liquid phase range, ionic liquids have become one of the most promising new reaction media. The term “green solvents†has been used to describe ionic liquids because of their negligible vapour pressure. Significant efforts have been made to design “fully greenâ€, non-toxic and biodegradable ionic liquids using renewable compounds as the starting materials. The synthesis of ionic liquids from environmentally sustainable and renewable raw materials is becoming more reasonable compared with the use of compounds derived from fossil feed stocks. Sugars appear to be suitable precursors for ionic liquids because they are among the most abundant and relatively inexpensive naturally occurring substances available. Research involving sugars for the preparation of ionic liquids has been limited and has only recently come to the forefront. There is continued pressure on chemical and pharmaceutical industries to reduce chemical waste and improve the selectivity and efficiency of synthetic processes. Case studies concerning the recoverable and recyclable catalysts for chemical processes like Diels-Alder reaction will be presented. The main emphasis will be placed on the application of ionic liquids as catalysts. The prevention of waste can be achieved if most of the reagents and the solvent are recyclable. The design and synthesis of recoverable catalysts will be demonstrated.